Open /etc/pacman.conf and append this
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[mate]
SigLevel = Optional TrustAll
Server = http://repo.mate-desktop.org/archlinux/$arch
2) Update pacman's database
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pacman -Sy
3) Make Mate SFS module, when finished change to /mnt/home and click to load
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makesb mate
4)Open /etc/rc.conf and replace: X_AUTOLOGIN="yes" with X_AUTOLOGIN="no"
5) Open /root/.xinitrc file, comment all text and add bellow:
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exec mate-session
6) Logout, and type alphaosx to start Mate desktop session